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RAS Chemistry & Material ScienceРасплавы Melts

  • ISSN (Print) 0235-0106
  • ISSN (Online) 3034-5715

Selection of the optimal composition of plasma coating of the Ni‒B‒Si system by the CALPHAD methods

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PII
S0235010625020021-1
DOI
10.31857/S0235010625020021
Publication type
Article
Status
Published
Authors
I. S. Bakhteev
  • Affiliation: Ural Federal University named after the first President of Russia B. N. Yeltsin
Нина Иосифовна Ильиных
  • Affiliation:
Volume/ Edition
Volume / Issue number 2
Pages
100-113
Abstract
Copper and alloys are widely used in parts of metallurgical equipment. Due to high heat capacity and reflectivity of IR radiation, copper parts have found application in water‒cooled blast furnace elements, such as tuyeres, which are subject to active gas‒abrasive, erosive and other types of wear and gas corrosion. Copper and its alloys have low resistance to wear and corrosion. To increase the resistance of copper parts, thermal barrier coatings of the Ni–B–Si, Ni–Cr–Al–Y and ZrO2 systems are offered. However, the first layers of the coating have low adhesion, and consequently, low strength of the first and subsequent layers. Laser remelting solves the problem of adhesion of the first layer to copper and the remaining layers to the fused layer. Using the CALPHAD methods in the TermoCalc software package (software version number 2024.1.132110‒55), the effect of reflow on the properties of the protective coating of the Ni‒B‒Si system was simulated. The following composition was chosen as the base: Ni – 86.97 at.%, B – 6.93 at.%, Si – 6.1 at.%. When laser radiation is applied to a coating applied by the gas‒thermal method, active interaction of the coating components with copper is observed, forming a continuous coating containing new phases and chemical elements. The appearance of some of these phases occasionally leads to cracking due to the formation of a stable compound of copper‒nickel alloy (monel metal), which has relatively low plasticity. Using X‒ray phase analysis data, it was confirmed that during the melting process, active mixing of the coating components (Ni–B–Si) with the substrate components (Cu) occurs, forming a stable compound of Cu with Ni. In this regard, using mathematical modeling, the density changes were predicted and the crystallization rates were determined using the Sheil method, as well as the phases formed during cooling in the coating, namely: Ni86.97‒B6.93‒Si6.1, Ni84.47‒Cu2.5‒B6.93‒Si6.1, Ni81.97Cu5B6.93Si6.1, Ni76.97Cu10B6.93Si6.1, Ni71.97Cu15B6.93Si6.1, Ni66.97Cu20B6.93Si6.1. Using calculation methods, based on the provisions of thermodynamics, the process of laser melting is described during heating from 1750 K to 3000 K and subsequent cooling from 1750 K to 500 K. When studying the melting process, for all compositions it was determined that a copper content in the coating of about 15‒20 at.% is favorable for the formation of a good quality coating, since at these concentrations the most complete release of copper atoms from the grain boundaries occurs, their transition to the surface layers of the coating and their binding with nickel into stable compounds of the monel‒metal type.
Keywords
газотермическое покрытие CALPHAD TermoCalc Cu Ni‒B‒Si лазерное оплавление поверхности монель‒металл рентгенофазовый анализ
Date of publication
17.09.2025
Year of publication
2025
Number of purchasers
0
Views
8

References

  1. 1. Appiah A.N.S., Wyględacz B., Matus K, Reimann Ł., Bialas O., Batalha G. F., Czupryński A., Adamiak M. Microstructure and performance of NiCrBSi coatings prepared by modulated arc currents using powder plasma transferred arc welding technology // Applied Surface Science. 2024. 648. №159065.
  2. 2. Ranjan R., Das A. K. Protection from corrosion and wear by different weld cladding techniques // Materials Today: Proceedings. 2022. 57 (4). P. 1687–1693.
  3. 3. Жук В.И. Анализ тепловой работы воздушных фурм доменной печи // Вестник Приазовского государственного технического университета. 2002. № 12. С. 25–30.
  4. 4. Li G., Huang P., Cheng P., Wu W., Zhang Y., Pang Zh., Xu Q., Zhu K., Zou X., Li R. Analysis of the failure mechanism of a blast furnace tuyere sleeve with protective coating // Engineering Failure Analysis. 2023. 153. 107537.
  5. 5. Chai Y.‒F., Zhang J., Ning X.‒J., Wei G.‒Y., Chen Y.‒T. Mechanism Research on Melting Loss of Coppery Tuyere Small Sleeve in Blast Furnace // High Temperature Materials and Processes. 2015. № 4.
  6. 6. Олейник К.И. Бахтеев И.С., Русских А.С., Осинкина Т.В., Жилина Е.М. Наплавление многокомпонентных сплавов, содержащих тугоплавкие металлы // Расплавы. 2024. №1. С. 90–100.
  7. 7. Chamkaur J., Sidhu B. S., Kumar P., Sidhu H. Performance of hardfaced/heat treated materials under solid particle erosion: A systematic literature review // Materials Today: Proceedings. 2022. 50. Part 2. P. 629–639.
  8. 8. Самедов Э.М. Повышение износостойкости воздушных фурм доменных печей путем создания защитного алюминиевого газотермического покрытия: дисс... канд. технич. наук : 05.02.13 / место защиты: Моск. гос. вечер. металлург. ин‒т. –Москва. 2007.
  9. 9. Cubero Á., Martinez, E., Fuente G. F., Cano, I. G., Dosta S. Angurel, L. Large enhancement of thermal conductance at ambient and cryogenic temperatures by laser remelting of plasma‒sprayed Al2O3 coatings on Cu // Materials Research Bulletin. 2021. 143. 111450.
  10. 10. Tahaei A., Vanani B. B., Abbasi M., Arizmendi‒Morquecho A. The hardfacing properties of the nickel‒based coating deposited by the PTA process with the addition of WC nano‒particles: Wear investigation // Tribology International. 2024. 193. 109472.
  11. 11. Guo H., Li B., Lu C., Zhou Q., Jia J. Effect of WC–Co content on the microstructure and properties of NiCrBSi composite coatings fabricated by supersonic plasma spraying // Journal of Alloys and Compounds. 2019. 789. P. 966 –975.
  12. 12. Jia D., Zhou D., Yi P., Zhang S., Zhan X., Liu Y. Effect of laser‒textured substrate on adhesion and microstructure of deposited Mo–NiCrBSiCFe coating // Journal of Alloys and Compounds. 2024. 29. P. 2072–2082
  13. 13. Yongfei J., Li J., Jiang Y.Q., Jia W.L., Lu, Z.J. Modified criterions for phase prediction in the multi‒component laser‒clad coatings and investigations into microstructural evolution/wear resistance of FeCrCoNiAlMox laser‒clad coatings // Applied Surface Science. 2019. 465. P. 700–714.
  14. 14. Balaguru S., Gupta M. Hardfacing studies of Ni alloys: A Critical Review // Journal of Materials Research and Technology. 2021. 10. P. 1210–1242.
  15. 15. Gu D., Meiners W., Wissenbach K., Poprawe R. Laser additive manufacturing of metallic components: Materials, processes and mechanisms // International Materials Reviews. 2012. 57. №3. P. 133–164.
  16. 16. Li N., Huang S., Zhang G., Qin R.Y., Liu W., Xiong H., Shi G., Blackburn J. Progress in additive manufacturing on new materials: A review // Journal of Materials Science & Technology. 2019. 35. №2. P. 242–269.
  17. 17. Kefeni K., Msagati T. A. M., Mamba B. Ferrite nanoparticles: Synthesis, characterisation and applications in electronic device // Materials Science and Engineering: B. 2017. 215. P. 37–55.
  18. 18. Wang T., Zhang J., Zhang Y., Chen S., Luo Z., Wu J., Zhu L., Lei J. Improving wear and corrosion resistance of LDEDed CrFeNi MEA through addition of B and Si // Journal of Alloys and Compounds. 2023. 968. 172223.
  19. 19. Lyu Y., Sun Y., Yang Y. Non‒vacuum sintering process of WC/W2C reinforced Ni‒based coating on steel // Metals and Materials International. 2016. 22. P. 311–318.
  20. 20. Zhang Z., Wang H. D., Xu B.S., Zhang G. S. Characterization of microstructure and rolling contact fatigue performance of NiCrBSi/WC–Ni composite coatings prepared by plasma spraying // Surface and Coatings Technology. 2015. 261. P. 60–68.
  21. 21. Kılıçay K., Buytoz S., Ulutan M. Microstructural and tribological properties of induction cladded NiCrBSi/WC composite coatings // Surface and Coatings Technology. 2020. 397. 125974.
  22. 22. Zhang L., Tianlu G., Zhou Z., Jiao K., Zhang J., Chen Y. Examination of factors and mechanisms contributing to surface wear on copper cooling staves within large blast furnaces // Engineering Failure Analysis. 2023. 157. 107922.
  23. 23. Rose D., Forth J., Henein H., Wolfe T., Qureshi A. J. Automated semantic segmentation of NiCrBSi‒WC optical microscopy images using convolutional neural networks // Computational Materials Science. 2022. 210. 111391.
  24. 24. Huang H., Singh S., Juhasz A., Roccisano A., Ang A., Stanford N. Influence of Copper Distribution in Thermally Sprayed Cu‒Bearing Coatings on Corrosion and Microbial Activity. // Surface and Coatings Technology. 2024. 478. 130430.
  25. 25. Hu D., Yan L., Chen H., Liu J., Mengchao W., Deng L. Microstructure and properties of Ta‒reinforced NiCuBSi + WC composite coating deposited on 5Cr5MoSiV1 steel substrate by laser cladding // Optics & Laser Technology. 2021. 142. 107210.
  26. 26. Texier D., Ecochard M., Gheno T., Monceau D., Salem M., Lours, P. Screening for Al2O3 failure in MCrAlY APS coatings using short‒term oxidation at high temperature // Corrosion Science. 2021. 184. 109334.
  27. 27. Zhang J., Wang R., Hu R., Zhang C., Li G., Zhang Y., Wu W. Failure mode and mechanism of a blast furnace tuyere // Engineering Failure Analysis. 2022. 137. 106294.
  28. 28. Zhang Z., Hao B., Chen H., Yuan H., Li L., Zhong M. Effect of granulometric composition of raw materials on performance of ceramic coating on copper prepared by slurry method // Surface and Coatings Technology. 2021. 417. 127178.
  29. 29. Краткий справочник физико‒химических величин / Сост. Н.М. Барон, Э.И. Квят, Е.А. Подгорная и др. ; Под ред. К. П. Мищенко и А. А. Равделя. – 6‒е изд., перераб. и доп. – Ленинград : Химия. Ленингр. Отделение. 1972.
  30. 30. Богомягков А.В. Пустовалов О.Д., Шумков А.А., Кайгородов А.К., Милованов Р.С. Влияние химического состава на жидкотекучесть алюминиевой бронзы / // Известия Самарского научного центра Российской Академии наук. 2015. 17. №2 (4).
  31. 31. Осинцев О.Е., Федоров В.Н. Медь и медные сплавы. Отечественные и зарубежные марки справочник / Изд. 2‒е, перераб. и доп. — Москва: Инновационное машиностроение. 2016.
  32. 32. Бахтеев И.С., Олейник К.И., Шак А.В., Фурман Е.Л., Валиев Р.М., Вопнерук А.А. Отработка режимов лазерного оплавления газотермического покрытия // Расплавы. 2024. №4. С. 451–466.
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