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RAS Chemistry & Material ScienceРасплавы Melts

  • ISSN (Print) 0235-0106
  • ISSN (Online) 3034-5715

EVALUATION OF THE POSSIBILITY OF FORMATION OF LOW-MELTING HIGH-ENTROPY ALLOYS OF THE AL-ZN-BI-PB-SN-IN-GA-SB SYSTEM

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PII
S30345715S0235010625050085-1
DOI
10.7868/S3034571525050085
Publication type
Article
Status
Published
Authors
N.I. Ilinykh
  • Affiliation: Vatolin Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences
S.A. Lelyukh
  • Affiliation: Vatolin Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences
I.A. Malkova
  • Affiliation: Vatolin Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences
B.R. Gelehinsky
  • Affiliation: Vatolin Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences
A.A. Rempel
  • Affiliation: Vatolin Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences
Volume/ Edition
Volume / Issue number 5
Pages
507-521
Abstract
Solders with a low melting point are necessary to solve the problem of integration of microcircuits and the reliability of their packaging, as well as to reduce thermal loads. To develop the next generation of electronic components, it is necessary to develop technologies for producing low-temperature compounds. This problem can be solved by creating solders, including those made of high-entropy alloys, differing in that they are characterized by the formation of solid solutions. These materials must be resistant to fatigue loads, exhibit plasticity, and adhere to other metallic materials. To reduce their toxicity, it is necessary to eliminate lead, which is usually found in solders. This paper presents the results of calculations of melting temperature, thermal conductivity, size factor δ, generalized thermodynamic parameter Ω, electronegativity, valence electron concentration, enthalpy, entropy, Gibb’s energy of mixing and other properties and parameters for 56 variants of five-component alloys of equiatomic composition from low-melting elements: Al, Zn, Bi, Pb, Sn, In, Ga and Sb, including, lead. The HEAPS program was used for the calculation, taking into account the inaccuracy in this program of the melting temperatures of tin, antimony, and indium, which differ from the observed ones. The VEC values for In, Sn, and Sb have been clarified. Based on the analysis of the calculated data, the compositions of potentially high-entropy alloys (HES) have been identified. It is shown that all alloys containing lead, as well as GaBiZnSnIn, GaBiZnSbIn, and AlGaBiZnIn alloys, do not satisfy the values of the δ parameter. They can form multiphase solid solutions, intermetallic compounds (IMC), and bulk-amorphous metallic glasses. The remaining variants of lead-free HEA-solders satisfy most parameters and can form solid solutions, with only AlGaZnSnSb being single-phase, and all others being multiphase solid solutions. The accumulated relatively large array of experimental and theoretical data can provide clarification of the criteria for the formation of the structure and properties of lead-free wind farms, which are in demand in practice.
Keywords
высокоэнтропийные сплавы (BЭC) легкоплавкие элементы неупорядоченные твердые растворы полуэмпирические параметры
Date of publication
01.05.2025
Year of publication
2025
Number of purchasers
0
Views
8

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